2,8,9-Tris(2-methylpropyl)-2,5,8,9-tetraaza-1λ5-phosphatricyclo[3.3.3.01,5]undecan-5-ium chloride dihydrate
نویسندگان
چکیده
The asymmetric unit of the title hydrated salt, C18H40N4P(+)·Cl(-)·2H2O, consists of two ionic mol-ecules and four water mol-ecules. The mol-ecular geometry around the penta-coordinate P atom is trigonal-bipyramidal, with a H atom and an apical N atom in axial positions and three N atoms with isobutyl substituents in equatorial positions. The Cl(-) ions and water mol-ecules are connected via O-H⋯Cl hydrogen bonds, forming chains along [100]. The ethyl-ene bridging groups are disordered with refined site-occupancy ratios of 0.578 (9):0.422 (9).
منابع مشابه
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